The formula this page uses
u · v = u₁v₁ + u₂v₂ + u₃v₃ cos θ = (u · v) / (|u| |v|) orthogonal ⟺ u · v = 0
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u · v = u₁v₁ + u₂v₂ + u₃v₃ cos θ = (u · v) / (|u| |v|) orthogonal ⟺ u · v = 0
Two vectors
For two vectors they mean the same thing. Orthogonal is preferred in higher dimensions and for functions, where drawing a right angle stops making sense but the dot product still works.
In 2D, swap the components and negate one: (3, 4) becomes (−4, 3). In 3D there is a whole plane of choices, so take the cross product with any vector that is not parallel to yours.
Its dot product with anything is 0, so by the algebraic definition yes. Geometrically it is meaningless, because the zero vector has no direction and there is no angle to measure.
Work. Push with force u along a displacement v and the energy transferred is u · v. Push at right angles and the dot product is zero, which is why carrying a bag horizontally does no work against gravity.